Spider-Man appears in two of the eight "Marvel Comics Presents" reprint comics. The other six are Captain America (with a Spidey Cameo), X-Men, Heathcliff, Care bears, Alf, and Flintstone Kids.
These books were sold in packs of 16 "Marvel Treats" (4 copies of each of 4 books). You can still find full packs of 16 on eBay from time to time at a reasonable price.
Pack One: Spider-Man/Scorpion, Care Bears, Heathcliff and Captain America.
Pack Two: Alf, Flintstone Kids, X-Men and Amazing Spider-Man #1.